Electrooptical and dielectric properties of comb-shaped mesogenic polymersin solutions and nematic melts

Citation
Nv. Tsvetkov et al., Electrooptical and dielectric properties of comb-shaped mesogenic polymersin solutions and nematic melts, POLYM SCI A, 42(7), 2000, pp. 714-717
Citations number
15
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
POLYMER SCIENCE SERIES A
ISSN journal
0965545X → ACNP
Volume
42
Issue
7
Year of publication
2000
Pages
714 - 717
Database
ISI
SICI code
0965-545X(200007)42:7<714:EADPOC>2.0.ZU;2-X
Abstract
A comparative study of the electrooptical end dielectric properties of the dilute solutions and nematic melts of two comb-shaped mesogenic polymers wa s performed by the methods of electric birefringence and orientational elas tic deformations in electric fields. For one of the polymers, an abnormal t emperature dependence of the threshold electric potential of nematic deform ation with a well-pronounced maximum was observed. It was shown that this m aximum is related to the occurrence of an extremum on the temperature depen dence of the orientational elasticity constant caused by fluctuations of sm ectic order in the polymeric nematic.