The effect of conditions of the hydrolytic polycondensation of methyltrichlorosilane on the sorption properties of synthesized silicon-containing polymers

Authors
Voronkov, MG Murinov, YI Pozhidaev, YN Anpilogova, GR Kolyadina, OA
Citation
Mg. Voronkov et al., The effect of conditions of the hydrolytic polycondensation of methyltrichlorosilane on the sorption properties of synthesized silicon-containing polymers, POLYM SCI A, 42(7), 2000, pp. 774-779
Citations number
24
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
POLYMER SCIENCE SERIES A
ISSN journal
0965545X → ACNP
Volume
42
Issue
7
Year of publication
2000
Pages
774 - 779
Database
ISI
SICI code
0965-545X(200007)42:7<774:TEOCOT>2.0.ZU;2-2
Abstract
Conditions of the hydrolytic polycondensation of methyltrichlorosilane (sol vent nature, order of reagent mixing) affect the composition and properties (specific surface, structure and volume of pores and microglobules, therma l stability) of the resulting poly(methyl silsesquioxane) and related incom plete condensation products with the general formula [CH3Si(OH)(n)O1.5-0.5n ](m) (n = 0. 1-0.6). Adsorption capacity of the polymer products was studie d with respect to phenol, Cd(II) and Pb(II) species, and molecular iodine.