Vy. Kotov, Calculation of activation-controlled reaction rate constants from parameters of electronic absorption spectra of ion pairs, RUSS CHEM B, 49(6), 2000, pp. 1002-1005
An equation relating the rate constants of a bimolecular activation-control
led redox reaction to the parameters directly determined from the electroni
c absorption spectra was obtained in the framework of the Marcus-Hush theor
y. Applicability of the equation for the prediction of redox reaction rare
constants was shown.