Aa. Fomkin et al., Adsorption deformation in the microporous carbon adsorbent - benzene system and porous structure of adsorbents, RUSS CHEM B, 49(6), 2000, pp. 1012-1016
The relative adsorption deformation of several microporous carbon adsorbent
s was studied as a function of the benzene adsorption at relative pressure
ranging from 1 . 10(-1) to 1.0 and at 293 K. A correlation between the maxi
mum compression of the sample and the characteristic energy of benzene adso
rption of the Dubinin-Radushkevich equation was obtained. Using data on the
adsorption deformation, it is possible to identify the region with a speci
fic pore size that cannot be evaluated with the help of the Dubinin-Radushk
evich equation.