Electrochemical potentials, optical transitions, and frontier orbitals of non-bridged and bridged bent sandwich zirconocene complexes

Authors
Loukova, GV Strelets, VV
Citation
Gv. Loukova et Vv. Strelets, Electrochemical potentials, optical transitions, and frontier orbitals of non-bridged and bridged bent sandwich zirconocene complexes, RUSS CHEM B, 49(6), 2000, pp. 1037-1039
Citations number
27
Categorie Soggetti
Chemistry
Journal title
RUSSIAN CHEMICAL BULLETIN
ISSN journal
10665285 → ACNP
Volume
49
Issue
6
Year of publication
2000
Pages
1037 - 1039
Database
ISI
SICI code
1066-5285(200006)49:6<1037:EPOTAF>2.0.ZU;2-0
Abstract
A linear correlation between the electrochemical gap values (G = E-ox - E-r ed) and the energies of optical transition in the UV-vis region was found a nd justified for a series of non-bridged and bridged bent-sandwich zirconoc ene complexes with the general formula R(eta(5)-L)(2)ZrX2, where L = cyclop entadienyl (Cp), indenyl (Ind), fluorenyl (Flu); X = Cl, Me; the bridging g roup R = SiMe2, (CH2)(2).