Synthesis and X-ray diffractometric studies of (1-x)A(2)Ti(2)O(7)-xFe(2)TiO(5) (A = Eu, Y) solid solutions.

Authors
Chtoun, E Hanebali, L Garnier, P
Citation
E. Chtoun et al., Synthesis and X-ray diffractometric studies of (1-x)A(2)Ti(2)O(7)-xFe(2)TiO(5) (A = Eu, Y) solid solutions., ANN CHIM-SC, 25(5), 2000, pp. 381-386
Citations number
8
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
ANNALES DE CHIMIE-SCIENCE DES MATERIAUX
ISSN journal
01519107 → ACNP
Volume
25
Issue
5
Year of publication
2000
Pages
381 - 386
Database
ISI
SICI code
0151-9107(200007/08)25:5<381:SAXDSO>2.0.ZU;2-3
Abstract
New solid solutions with pyrochlore structure have been evidenced in the tw o binary systems Y2Ti2O7 - Fe2TiO5 et Eu2Ti2O7 - Fe2TiO5. The domain of com position of the solid solutions was defined by X-ray diffraction, 0-33 and 0-40% (Fe2TiO5), respectively, for Y2Ti2O7 et Eu2Ti2O7 The space group of t he solid solutions is Fd3m. A contraction of the cubic cell parameters is o bserved for the two solid solutions which are non-stoichiometric.