The selective deposition of compound semiconductors on single crystal
silicon tip arrays produces optical quality, direct band gap materials
on the silicon nanostructures. We demonstrate using the organometalli
c vapor phase epitaxy of GaInP that the direct band gap semiconductor
nucleates selectively on the silicon tips. The structural properties o
f the tips (whose radius of curvature is approximately 10-20 nm) are u
naltered by this chemical vapor deposition process. Furthermore, inten
se band edge emission from the GaInP is observed with an external elec
tron beam or laser stimulation indicating a good crystal quality for t
he three dimensional epitaxial structures. (C) 1997 American Institute
of Physics.