Intramolecular carbometalation of functionalized terminal alkynes via low-valent titanium complexes

Authors
Morlender-Vais, N Solodovnikova, N Marek, I
Citation
N. Morlender-vais et al., Intramolecular carbometalation of functionalized terminal alkynes via low-valent titanium complexes, CHEM COMMUN, (19), 2000, pp. 1849-1850
Citations number
27
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
19
Year of publication
2000
Pages
1849 - 1850
Database
ISI
SICI code
1359-7345(2000):19<1849:ICOFTA>2.0.ZU;2-W
Abstract
Treatment of delta- and gamma-functionalized monosubstituted alkynes with d iisopropoxy(eta(2)-propene)titanium induces an intramolecular cyclisation t o afford the 4- and 5-membered cycloalkanols in good overall yields.