First tether-directed regioselective bis-functionalisation of C-70: effects of cation complexation on the redox properties of diastereoisomeric fullerene crown ether conjugates

Authors
van Eis, MJ Alvarado, RJ Echegoyen, L Seiler, P Diederich, F
Citation
Mj. Van Eis et al., First tether-directed regioselective bis-functionalisation of C-70: effects of cation complexation on the redox properties of diastereoisomeric fullerene crown ether conjugates, CHEM COMMUN, (19), 2000, pp. 1859-1860
Citations number
24
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
19
Year of publication
2000
Pages
1859 - 1860
Database
ISI
SICI code
1359-7345(2000):19<1859:FTRBOC>2.0.ZU;2-Q
Abstract
The covalently templated bis-functionalisation of C-70, employing a dibenzo -18-crown-6 tether, proceeds with complete regiospecificity and provides a bis-addition pattern which is disfavoured in sequential transformations.