New highly active chiral phosphapalladacycle catalysts. First isolation and characterization of a Pd(IV) intermediate

Authors
Brunel, JM Hirlemann, MH Heumann, A Buono, G
Citation
Jm. Brunel et al., New highly active chiral phosphapalladacycle catalysts. First isolation and characterization of a Pd(IV) intermediate, CHEM COMMUN, (19), 2000, pp. 1869-1870
Citations number
30
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
19
Year of publication
2000
Pages
1869 - 1870
Database
ISI
SICI code
1359-7345(2000):19<1869:NHACPC>2.0.ZU;2-R
Abstract
The synthesis and characterization of a new active P*-active phosphapallada cycle and its successful use in the asymmetric hydroarylation of norbornene with turnover numbers (TONs) of up to 10(10) is described.