Synthesis of quinolines via ruthenium-catalysed amine exchange reaction between anilines and trialkylamines

Authors
Cho, CS Oh, BH Kim, JS Kim, TJ Shim, SC
Citation
Cs. Cho et al., Synthesis of quinolines via ruthenium-catalysed amine exchange reaction between anilines and trialkylamines, CHEM COMMUN, (19), 2000, pp. 1885-1886
Citations number
31
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
19
Year of publication
2000
Pages
1885 - 1886
Database
ISI
SICI code
1359-7345(2000):19<1885:SOQVRA>2.0.ZU;2-4
Abstract
Anilines react with an array of trialkylamines in the presence of a catalyt ic amount of RuCl3. nH(2)O and bis(diphenylphosphino)methane together with SnCl2. 2H(2)O and hex-1-ene as hydrogen acceptor in dioxane at 180 degrees C to afford the corresponding 2,3-disubstituted quinolines in moderate to g ood yields.