Citation
S. Gomez et al., Gold nanoparticles from self-assembled gold(I) amine precursors, CHEM COMMUN, (19), 2000, pp. 1945-1946
Citations number
30
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345
→ ACNP
Issue
19
Year of publication
2000
Pages
1945 - 1946
Database
ISI
SICI code
1359-7345(2000):19<1945:GNFSGA>2.0.ZU;2-O
Abstract
The reaction of AuCl(THT) (1) with long chain primary amines (CnH2n+1NH2; n
= 8, 12, 16) leads to the formation of the complexes AuCl(NH2R) (R = C8H17
, 2; C12H25, 3; C16H33, 4) which are characterized by classical methods and
shown to self-organize in the solid state into a fibrous material; decompo
sition of the complexes inside the supramolecular framework yields a monola
yer of ordered gold nanoparticles.