SYNTHESIS OF THE ZIEGLER KEY INTERMEDIATE AND RELATED PRECURSORS FOR THE SYNTHESIS OF FORSKOLIN AND ERIGEROL IN ENANTIOMERICALLY PURE FORM

Authors
PREITE MD RUVEDA EA
Citation
Md. Preite et Ea. Ruveda, SYNTHESIS OF THE ZIEGLER KEY INTERMEDIATE AND RELATED PRECURSORS FOR THE SYNTHESIS OF FORSKOLIN AND ERIGEROL IN ENANTIOMERICALLY PURE FORM, Synthetic communications, 24(19), 1994, pp. 2809-2825
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthetic communications → ACNP
ISSN journal
00397911
Volume
24
Issue
19
Year of publication
1994
Pages
2809 - 2825
Database
ISI
SICI code
0039-7911(1994)24:19<2809:SOTZKI>2.0.ZU;2-P
Abstract
The Ziegler key intermediate 5, previously used in three total synthes is of forskolin (1), and the intermediate 4, potentially useful for th e synthesis of erigerol (2), were obtained in optically pure form by t he resolution of the allylic alcohol 7a with R-(-)-O-methylmandelic ac id.