The paper is concerned with the line shapes of resonance phenomena observed
in Coherent Population Trapping (CPT) applied to alkali atoms in a cell co
ntaining a buffer gas. Significant asymmetries and departures from a Lorent
zian shape have been observed in connection with the measurement of dark li
nes and CPT maser emission profiles. Measurements are reported as a functio
n of the power and frequency tuning of the laser used to create the CPT phe
nomenon. The paper reports on different experimental conditions and a compa
rison between theory and experiments is made for the cases of cesium and ru
bidium in a buffer gas.