B. De Beauvoir et al., Metrology of the hydrogen and deuterium atoms: Determination of the Rydberg constant and Lamb shifts, EUR PHY J D, 12(1), 2000, pp. 61-93
We present a detailed description of several experiments which have been pr
eviously reported in several letters: the determination of the 1S Lamb shif
t in hydrogen by a comparison of the frequencies of the 1S-3S and 2S-6S or
2S-6D two-photon transitions, and the measurement of the 2S-8S/D and 2S-12D
optical frequencies. Following a complete study of the lineshape of the tw
o-photon transitions, we provide the updated values of these frequencies wh
ich have been used in the 1998 adjustment of the fundamental constants. Fro
m an analysis taking into account these results and several other precise m
easurements by other authors, we show that the optical frequency measuremen
ts have superseded the microwave determination of the 2S Lamb shift and we
deduce optimized values for the Rydberg constant, R-infinity = 109737.315 6
85 50(84) cm(-1) (relative uncertainty of 7.7 x 10(-12)) and for the 1S and
2S Lamb shifts L(1S) = 8172.840(22) MHz and L(2S-2P) = 1057.8450(29) MHz (
respectively, 8183.970(22) MHz and 1059.2341(29) MHz for deuterium). These
are now the most accurate values available.