The effect of anti-inhibition of radiolytic hydrogen formation in liquids

Citation
Vm. Byakov et al., The effect of anti-inhibition of radiolytic hydrogen formation in liquids, HIGH ENERG, 34(5), 2000, pp. 284-289
Citations number
29
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
HIGH ENERGY CHEMISTRY
ISSN journal
00181439 → ACNP
Volume
34
Issue
5
Year of publication
2000
Pages
284 - 289
Database
ISI
SICI code
0018-1439(200009/10)34:5<284:TEOAOR>2.0.ZU;2-G
Abstract
Attention is focused on that the phenomenon known as anti-inhibition in pos itronium chemistry is also observed in the radiolyses of liquids. In partic ular, the yield of radiolytic hydrogen from cyclohexane in the presence of molecular iodine increases when benzene is added to a cyclohexane solution. This effect is rationalized on the basis of the previously advanced idea o n the similarity between the formation mechanisms of positronium and radiol ytic hydrogen. The assumption that the enhancement of radiolytic hydrogen y ield in aqueous nitrate or nitrite solutions taking place upon addition of Mn2+, Co2+, Zn2+, etc. ions is also the manifestation of the anti-inhibitio n effect, which has been known neither for positronium nor for radiolytic h ydrogen in polar media, is substantiated.