A precise and sensitive solvent extraction-colourimetric technique has been
developed for the determination of dissolved copper in saline waters, usin
g a reagent of established selectivity. The limit of detection and operatin
g range of the technique have been improved to cover copper concentrations
found in estuaries and contaminated coastal waters. The limit of detection
of the technique is estimated as 0.5 mu g l(-1). Data for spiking recovery
and long term standard deviation of determination are reported. Analytical
data produced by this technique for over forty estuarine samples are compar
ed with corresponding analyses by graphite furnace atomic absorption spectr
ophotometry.