We systematically studied amorphous silicon (a-Si:H) films and solar cells
which were fabricated by H-2-diluted SiH4 plasma. The H-2 dilution improves
the quality of poor materials resulting from non optimized pure SiH4 condi
tions however this improvement can also be achieved by reducing the RF powe
r under pure SiH4 conditions. The H-2 dilution is not always necessary for
the optimization of a-Si:H. Higher diluted plasma reduces the optical absor
ption coefficient of a-Si:H, resulting in a lower short circuit current (I-
sc), and the H-2-dilution conditions could not give higher conversion effic
iency (Eff) than the optimized pure SiH4 condition. The H-2-diluted plasma
at a relatively low pressure (0.2 Torr) causes a lower open circuit voltage
(V-oc) in spite of wider optical gaps and lower I-sc than values estimated
from the optical absorption coefficient, probably due to the damage of und
erlying layers by H ions or radicals. These plasma damages are suppressed b
y increasing the pressure up to similar to 1.0 Torr.