Second-order Raman spectra corresponding to transverse acoustic phonons are
studied in detail for crystalline Si over the temperature range 20-620 deg
rees C. The largest relative softening and anharmonicity at the boundaries
of the Brillouin zone were observed for the TA(X) mode. Extrapolation of th
e TA(X) frequency to high temperatures suggests that the Si lattice should
be dynamically unstable at temperatures on the order of a doubled melting t
emperature. It is found that the main contribution to the softening of the
transverse acoustic phonons in silicon comes from the anharmonicity and not
from the volume expansion. (C) 2000 MAIK "Nauka/Interperiodica".