A large-displacement electrochemical actuator was designed, fabricated, and
tested. The large displacement is obtained by using a corrugated membrane
made by physical vapor deposition of Parylene sandwiched with an intermedia
te layer of sputtered platinum. The layered structure is approximately 8-mu
m thick, with 26 grooves approximately 120-mu m deep, and with a radial pe
riod of 350 mu m. The electrochemical cell consists of platinum electrodes
with a 1 M H2SO4 solution. Hydrogen and oxygen gas is generated to displace
the membrane. Although the actuator can operate at a voltage as low as 1.2
3 V, the experimentally determined efficiency of converting electrical ener
gy to mechanical work is only 0.37%. The governing equations for the conser
vation of mass, momentum (equilibrium), energy, and the entropy generation
rate were formulated assuming that the gas bubbles either nucleate without
growth or grow without nucleation. For the nucleation case, simulations wer
e performed for constant pressure isothermal actuation, and the average exp
erimental efficiency was bounded by simulations with gas bubble radii betwe
en 1 x 10(-5) m and 1 x 10(-6) m. The predicted ratio of the power dissipat
ed to the electrical power supplied is 1.37 for isothermal actuation.