We study the diffusion of Brownian particles on the surface of a sphere and
compute the distribution of solid angles enclosed by the diffusing particl
es. This function describes the distribution of geometric phases in two-sta
te quantum systems (or polarized light) undergoing random evolution. Our re
sults are also relevant to recent experiments which observe the Brownian mo
tion of molecules on curved surfaces such as micelles and biological membra
nes. Our theoretical analysis agrees well with the results of computer expe
riments.