The structure of the LiOMe center dot 2MeOH crystal solvate. A new structural type for tetrameric alkoxides

Authors
Starikova, ZA Turevskaya, EP Turova, NY Yanovsky, AI
Citation
Za. Starikova et al., The structure of the LiOMe center dot 2MeOH crystal solvate. A new structural type for tetrameric alkoxides, J CHEM S DA, (19), 2000, pp. 3237-3238
Citations number
12
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
ISSN journal
1470479X → ACNP
Issue
19
Year of publication
2000
Pages
3237 - 3238
Database
ISI
SICI code
1470-479X(2000):19<3237:TSOTLC>2.0.ZU;2-X
Abstract
The solvate LiOMe . 2MeOH (1) was isolated from a solution of LiOMe in MeOH , its tetrameric unit [Li-4(mu-OR)(4)(mu-ROH)(2)(ROH)(4)]. 2ROH may be desc ribed as two distorted squares [Li-2(mu-OR)(mu-ROH)], linked by bridging al koxy groups and two hydrogen bonds; 1 easily loses the solvate alcohol yiel ding polymeric LiOMe.