C. Branger et al., POLYURETHANES CONTAINING BORON CHROMOPHORES AS SIDE-CHAINS FOR NONLINEAR OPTICS, Chemical physics letters, 272(3-4), 1997, pp. 265-270
An axo-dye containing dimesityl boron as the electron acceptor group i
s synthesized and incorporated as side chains in polyurethane matrices
. These new polymers have been poled under an external electrical fiel
d by the corona technique. They exhibit high nonlinear response and a
remarkable temporal stability. It appears that the poling time is a cr
ucial parameter not only in terms of obtaining a good second harmonic
response but also in the temporal stability. (C) 1997 Elsevier Science
B.V.