N. Tatsuda et al., Recycling technology for laminates composed of thermoplastic polyolefin elastomer and crosslinked polypropylene foam, KOBUNSH RON, 57(9), 2000, pp. 561-568
The laminates composed of thermoplastic polyolefin elastomer (TPO) skin lay
ers and crosslinked polypropylene (PP) foam layers have often been used for
inner components of automobiles, such as instrument panels and door trim.
In recycling the laminates by a simple melt-kneading method, the recycled m
aterial shows very poor mechanical properties, because the PP foam cannot b
e dispersed into the TPO matrix due to its crosslinked structure. In this s
tudy, a new recycling technology has been developed by using reactive extru
der to eliminate the deterioration of mechanical property. This technology
is based on resolving the crosslinked structure of PP foam by a reactive ag
ent injected into the extruder, and finely dispersing decrosslinked PP foam
into the TPO matrix by high shear force. Such reactive processing is also
useful for decomposing azodicarbonamide, which is used as foaming agent for
PP foam and causes deterioration of the surface flatness and the light res
istance of TPO. The recycled material shows the properties similar to those
of TPO. It is possible to use the recycled materials in place of TPO skin
layers.