HINDERED PHENOLS - MODELING INHIBITION-MECHANISM

Citation
Vv. Kharitonov et al., HINDERED PHENOLS - MODELING INHIBITION-MECHANISM, Polymer-plastics technology and engineering, 36(4), 1997, pp. 527-546
Citations number
19
Categorie Soggetti
Polymer Sciences
ISSN journal
03602559
Volume
36
Issue
4
Year of publication
1997
Pages
527 - 546
Database
ISI
SICI code
0360-2559(1997)36:4<527:HP-MI>2.0.ZU;2-L
Abstract
The inhibition mechanism of hindered phenols in polymers and low-molec ular compounds can be studied by using the procedures developed to stu dy complicated processes of chain oxidation and inhibition in hydrocar bon materials. At each temperature (mechanism strongly depends on temp erature and other factors) the key reactions of antioxidant actions we re identified and corresponding kinetic parameters determined. The ana lysis showed how the effectiveness of hindered phenoles changes as a f unction of temperature.