A new theory is introduced for the onset of electrical conduction in isotro
pic conductive adhesives, based on the observation that conduction is a res
ult of the creation of conducting contacts in metal-insulator composite adh
esives. The present theory resolves several prevalently contradicting issue
s including the onset dependency of electrical conduction on the volume fra
ction of filler particles, the particle size, the pressure effect, and the
type of insulator matrix of an adhesive. The theory also predicts the condi
tion for the occurrence of two percolation thresholds. (C) 2000 Elsevier Sc
ience Ltd. All rights reserved.