Synthesis and molecular structure of the amido-bridged dinuclear rhodium complex [Cp*Rh{mu(2)-(NH)(2)C10H6-2,3}(mu(2)-Cl)RhCp*][PF6] (Cp* = eta(5)-C5Me5)

Authors
Matsuzaka, H Kamura, T Ariga, K Okubo, T Ishii, T Yamashita, M Kondo, M Kitagawa, S
Citation
H. Matsuzaka et al., Synthesis and molecular structure of the amido-bridged dinuclear rhodium complex [Cp*Rh{mu(2)-(NH)(2)C10H6-2,3}(mu(2)-Cl)RhCp*][PF6] (Cp* = eta(5)-C5Me5), MOLEC CRYST, 342, 2000, pp. 1-6
Citations number
6
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
MOLECULAR CRYSTALS AND LIQUID CRYSTALS → ACNP
Volume
342
Year of publication
2000
Pages
1 - 6
Database
ISI
SICI code
Abstract
Reaction of [Cp*RhCl2](2) (1) with (LiNH)(2)C10H6-2,3 gives the mononuclear species Cp*Rh(NH)(2)C10H6-2,3 (3), which is selectively converted to the a mido-bridged dinuclear Rh(III) complex [Cp*Rh{mu(2)-(NH)(2)C10H6-2,3}(mu(2) -Cl)RhCp*]PF6 (4; Cp* = eta(5)-C5Me5) upon treatment with 1/AgPF6 in aceton e. The molecular structure of 4 has been determined by X-ray crystallograph y.