Synthesis and magnetic property of adducts of ruthenium(II,III) pivalate with 9,10-anthraquinone

Authors
Yoshioka, D Handa, M Azuma, H Mikuriya, M Hiromitsu, I Kasuga, K
Citation
D. Yoshioka et al., Synthesis and magnetic property of adducts of ruthenium(II,III) pivalate with 9,10-anthraquinone, MOLEC CRYST, 342, 2000, pp. 133-138
Citations number
10
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
MOLECULAR CRYSTALS AND LIQUID CRYSTALS → ACNP
Volume
342
Year of publication
2000
Pages
133 - 138
Database
ISI
SICI code
Abstract
Reaction of tetrakis(pivalato)diruthenium(II,III) cation dimer and 9,10-ant hraquinone (aq) gave two kinds of adducts, [{Ru-2(piv)(4)(H2O)}(2)(aq)]-(BF 4)(2) (1) (pivH = pivalic acid) and [Ru-2(piv)(4)(aq)](n) (2), depending on the condition. Very weak antiferromagnetic interaction was observed for 1. The X-ray crystal structure of 2 shows an one-dimensional chain structure.