Synthesis of hyperbranched platinum-poly(yne) polymers by self polycondensation

Authors
Onitsuka, K Ohshiro, N Fujimoto, M Takei, F Takahashi, S
Citation
K. Onitsuka et al., Synthesis of hyperbranched platinum-poly(yne) polymers by self polycondensation, MOLEC CRYST, 342, 2000, pp. 159-166
Citations number
14
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
MOLECULAR CRYSTALS AND LIQUID CRYSTALS → ACNP
Volume
342
Year of publication
2000
Pages
159 - 166
Database
ISI
SICI code
Abstract
A hyperbranched polymer constructed by platinum-acetylide units has been sy nthesized by self polycondensation of a dinuclear platinum complex having o ne terminal acetylene and two platinum-chloride groups as an AB(2) monomer in the presence of a copper catalyst in amine. The hyperbranched polymer is soluble in common organic solvents and characterized by means of spectral analyses and GPC.