Synthesis, structure and magnetism of new bimetallic assemblies, [Ni(chxn)(2)](3)[M(CN)(6)](2)center dot 2H(2)O (chxn=1,2-trans-cyclohexane-diamine; M-III= Fe, Co)

Authors
Fukita, N Ohba, M Okawa, H
Citation
N. Fukita et al., Synthesis, structure and magnetism of new bimetallic assemblies, [Ni(chxn)(2)](3)[M(CN)(6)](2)center dot 2H(2)O (chxn=1,2-trans-cyclohexane-diamine; M-III= Fe, Co), MOLEC CRYST, 342, 2000, pp. 217-224
Citations number
9
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
MOLECULAR CRYSTALS AND LIQUID CRYSTALS → ACNP
Volume
342
Year of publication
2000
Pages
217 - 224
Database
ISI
SICI code
Abstract
A new type of cyanide-bridged bimetallic assemblies, [Ni(chxn)(2)](3)[M(CN) (6)](2).2H(2)O (chxn = 1,2-trans-cyclohexanediamine; M3+-Fe (1), Co (2)), h ave been prepared. The X-ray crystallography for the assemblies has proved a 2-D network comprised of M6Ni6 dodecagon units extended by M-CN-Ni linkag e. Compound 1 shows a ferromagnetic spin-exchange interaction between the a djacent Fe(III) and Ni(II) ions through cyanide bridge and a long-range mag netic ordering below 13.1 K.