First crystal structure of a Tb3+ complex derived from an aromatic hydroxamate ligand: sensitized luminescence properties

Authors
Tedeschi, C Picard, C Azema, J Donnadieu, B Tisnes, P
Citation
C. Tedeschi et al., First crystal structure of a Tb3+ complex derived from an aromatic hydroxamate ligand: sensitized luminescence properties, NEW J CHEM, 24(10), 2000, pp. 735-737
Citations number
27
Categorie Soggetti
Chemistry
Journal title
NEW JOURNAL OF CHEMISTRY
ISSN journal
11440546 → ACNP
Volume
24
Issue
10
Year of publication
2000
Pages
735 - 737
Database
ISI
SICI code
1144-0546(2000)24:10<735:FCSOAT>2.0.ZU;2-C
Abstract
The neutral terbium complex [Tb(op)(3)]. 3H(2)O derived from the 1-hydroxy- 2(1H)-pyridinone ligand displays a good luminescent quantum yield (Phi=0.41 in MeOD solution), due to an efficient energy transfer through the hydroxa mate linkage. The coordination properties of the hydroxamate functionality were established by X-ray analysis.