Atomic force microscope evidence for the existence of smecticlike surface layers in the isotropic phase of a nematic liquid crystal

Using a temperature controlled atomic force microscope we have observed pre smectic layering in the isotropic phase of 4-cyano-4'-n-octylbiphenyl (8CB) on silanated glass. The first molecular layer shows a smecticlike compress ibility modulus of B approximate to 10(7) N/m(2) and is stable more than 20 K beyond the bulk clearing point. It is followed by a presmectic modulatio n that increases when cooling towards the isotropic-nematic transition. In the bulk isotropic phase, the layers cover approximately 70% of the glass s urface, indicating a clusterlike organization.