The changes of defects in PbWO4 crystal caused by La dopant have been studi
ed by means of positron annihilation lifetime and X-ray photoelectron spect
rum (XPS). The results show that La dopant enhance the concentration of lea
d vacancy (V-Pb) which can be described as the positron capture center in P
bWO4 crystal,and lead vacancy will furthermore introduce low-valent oxygen
center. We discuss the mechanism of La doped in PbWO4, and consider that ox
ygen vacancy is restrained by doping of La, while lead vacancy density is i
ncreased by La dopant.