Cyclopalladation of Schiff base ligands: crystal and molecular structures of [Pd-{2,4-(OCH3)(2)C6H2C(H)=N(C6H11)-C-6,N} (mu-O2CCH3)](2) and [Pd-{3,4-(OCH3)(2)C6H2C(H)=N(C6H11)-C-6,N}(mu-O2CCH3](2)

Authors
Mosteiro, R Perille, E Fernandez, A Lopez-Torres, M Vila, JM Suarez, A Ortigueira, JM Pereira, MT Fernandez, JJ
Citation
R. Mosteiro et al., Cyclopalladation of Schiff base ligands: crystal and molecular structures of [Pd-{2,4-(OCH3)(2)C6H2C(H)=N(C6H11)-C-6,N} (mu-O2CCH3)](2) and [Pd-{3,4-(OCH3)(2)C6H2C(H)=N(C6H11)-C-6,N}(mu-O2CCH3](2), APPL ORGAN, 14(10), 2000, pp. 634-639
Citations number
26
Categorie Soggetti
Chemistry
Journal title
APPLIED ORGANOMETALLIC CHEMISTRY
ISSN journal
02682605 → ACNP
Volume
14
Issue
10
Year of publication
2000
Pages
634 - 639
Database
ISI
SICI code
0268-2605(200010)14:10<634:COSBLC>2.0.ZU;2-F
Abstract
X-ray diffraction studies show that the title cyclometallated compounds sho w each palladium atom C,N-bonded to a deprotonated Schiff base ligand, The molecular configuration is a dimeric form of the anti isomer with the cyclo palladated moieites in an 'open-book' arrangement linked by two acetate bri dging ligands, Copyright (C) 2000 John Wiley & Sons, Ltd.