We have studied ultraviolet photoluminescence from high-purity zinc-oxide p
owder over a wide temperature range (2-293 K). At low temperatures, the spo
ntaneous emission is due to radiative recombination of excitons bound to do
nors and acceptors. At high temperature (> 90 K), it mainly consists of rec
ombination of free excitons, with exciton-exciton collision-induced recombi
nation dominating the spectrum at higher pumping intensities. Emission from
the exciton-exciton collision process shows clear stimulated-emission beha
vior. At sufficiently high pumping intensity, the stimulated emission band
shifts abruptly to a longer wavelength due to the formation of an electron-
hole plasma. Sharp emission peaks are observed in the stimulated emission b
ands. The possible origins of these sharp peaks are discussed. (C) 2000 Ame
rican Institute of Physics. [S0003-6951(00)01341-3].