A systematic investigation of the effect of rapid thermal annealing (RTA) o
n optical properties of undoped GaNAs/GaAs structures is reported. Two effe
cts are suggested to account for the observed dramatic improvement in the q
uality of the GaNxAs1-x/GaAs quantum structures after RTA: (i) improved com
position uniformity of the GaNxAs1-x alloy, deduced from the photoluminesce
nce (PL), PL excitation and time-resolved measurements; and (ii) significan
t reduction in the concentration of competing nonradiative defects, reveale
d by the optically detected magnetic resonance studies. (C) 2000 American I
nstitute of Physics. [S0003-6951(00)00441-1].