Solid-liquid interface velocity and diffusivity in laser-melt amorphous silicon

We studied the microscopic kinetics of the amorphous-liquid interface in su percooled laser-melt silicon by means of molecular dynamics computer simula tions. The interface velocity was obtained as a function of temperature by direct simulation of the interface motion in an amorphous-liquid model syst em. The temperature dependence of the kinetic prefactor was extracted from the interface velocity function and compared to the values of self-diffusiv ity obtained from independent molecular dynamics simulations of bulk amorph ous Si. The kinetic prefactor for interfacial diffusion shows a distinctly non-Arrhenius behavior which is attributed to Fulcher-Vogel kinetics in the supercooled liquid. (C) 2000 American Institute of Physics. [S0003- 6951(0 0)04641-6].