Dm. Shen et Lvc. Rees, FREQUENCY-RESPONSE STUDY OF SINGLE-FILE DIFFUSION IN THETA-1, Journal of the Chemical Society. Faraday transactions, 90(19), 1994, pp. 3017-3022
Citations number
18
Categorie Soggetti
Chemistry Physical","Physics, Atomic, Molecular & Chemical
Diffusion of nitrogen, carbon monoxide and carbon dioxide molecules in
theta-1, a zeolite with a one-dimensional 10-ring channel network, ha
s been investigated using the frequency response (FR) method. Surface
barrier effects have been observed from the frequency response spectra
in theta-1, where single-file diffusion may apply. The temperature an
d concentration dependences of diffusion coefficients and surface barr
iers have been discussed. The diffusivities and activation energies of
CO and CO2 diffusion in theta-1 determined by FR method are compared
with those measured by the FR and pulsed field gradient (PFG) NMR meth
ods in silicalite-1 which has 10-ring pores which, however, are inters
ected.