Small bitumen droplets, roughly 10 to 40 mu m in diameter, constitute a sig
nificant fraction of the total hydrocarbon in an oil sands flotation proces
s. In this study, the aeration of such droplets is examined-both from a sur
face energetic perspective as well as from direct observations. The spreadi
ng coefficient associated with bitumen aeration is evaluated based on in si
tu measurements of interfacial and surface tensions. In addition, micropipe
tte techniques are employed to monitor the aeration process and to quantify
the probability of aeration. Our results suggest that a positive spreading
coefficient does not always guarantee the aeration of bitumen droplets, an
d that such a process may best be described from a statistical stand point.