Preparation and characterization of mono-imidazole ligated (meso-tetramesitylporphyrinato)iron(III) complexes: Model for cytochromes c '

Authors
Ikezaki, A Nakamura, M
Citation
A. Ikezaki et M. Nakamura, Preparation and characterization of mono-imidazole ligated (meso-tetramesitylporphyrinato)iron(III) complexes: Model for cytochromes c ', CHEM LETT, (9), 2000, pp. 994-995
Citations number
19
Categorie Soggetti
Chemistry
Journal title
CHEMISTRY LETTERS
ISSN journal
03667022 → ACNP
Issue
9
Year of publication
2000
Pages
994 - 995
Database
ISI
SICI code
0366-7022(20000905):9<994:PACOML>2.0.ZU;2-J
Abstract
A series of mono-imidazole ligated (meso-tetramesityl-porphyrinato)iron(III ) complexes have been prepared. The spin states of these complexes are pres ented as the admired intermediate (S = 3/2, 5/2) on the basis of the H-1 NM R, C-13 NMR, EPR, and magnetic moments. The S = 3/2 character has increased as the axial imidazole ligand becomes bulkier.