A novel hydrogen-bonded duplex made up of water molecules and halide ions in the sandwich inclusion structures of (C10H8N3S)(+)center dot X center dot 2H(2)O [X=Cl-, Br-]

Authors
Prabakaran, P Murugesan, S Robert, JJ Panneerselvam, P Muthiah, PT Bocelli, G Righi, L
Citation
P. Prabakaran et al., A novel hydrogen-bonded duplex made up of water molecules and halide ions in the sandwich inclusion structures of (C10H8N3S)(+)center dot X center dot 2H(2)O [X=Cl-, Br-], CHEM LETT, (9), 2000, pp. 1080-1081
Citations number
11
Categorie Soggetti
Chemistry
Journal title
CHEMISTRY LETTERS
ISSN journal
03667022 → ACNP
Issue
9
Year of publication
2000
Pages
1080 - 1081
Database
ISI
SICI code
0366-7022(20000905):9<1080:ANHDMU>2.0.ZU;2-X
Abstract
The X-ray crystal structures of thiabendazolium halide dihydrates (C10H8N3S )(+). X . 2H(2)O [X = Cl-, Br-] 1, 2 reveal a novel hydrogen-bonded duplex consisting of alternate edge-sharing (H2O . X)(2) quadrilaterals and (2H(2) O . X)(2) hexagons; notably these duplexes exist as host lattices and sandw ich thiabendazole molecules into two different supramolecular architectures by similar N ... X and N ... O hydrogen bonds.