MECHANISM OF THERMAL-DECOMPOSITION OF DIPHENYLDIAZOMETHANE IN THE PRESENCE OF OXYGEN

Authors
KOMISSAROV VD NAZAROV AM YAMILOVA GA
Citation
Vd. Komissarov et al., MECHANISM OF THERMAL-DECOMPOSITION OF DIPHENYLDIAZOMETHANE IN THE PRESENCE OF OXYGEN, Russian chemical bulletin, 46(2), 1997, pp. 261-264
Citations number
26
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
46
Issue
2
Year of publication
1997
Pages
261 - 264
Database
ISI
SICI code
1066-5285(1997)46:2<261:MOTODI>2.0.ZU;2-3
Abstract
The kinetics, products, and mechanism of thermal decomposition of diph enyldiazomethane (RN2, R = Ph2C) in the presence of oxygen were studie d. Thermolysis is accompanied by chemiluminescence. An emitter of chem iluminescence ((RO)-R-3) forms in the reaction of benzophenone O-oxide (R) over dotO(O) over dot with RN2.