Positron and positronium chemistry by quantum Monte Carlo. V. The ground state potential energy curve of e(+)LiH

The potential energy curve of e(+)LiH has been computed by means of diffusi on Monte Carlo using explicitly correlated trial wave functions. This curve allows us to compute the adiabatic total and binding energies and the vibr ational spectrum of e(+)LiH, and the adiabatic positron affinity of LiH. Us ing these results, we discuss the possibility to detect spectroscopically e (+)LiH in the gas phase, in order to have the first direct observation of a positron-containing system. (C) 2000 American Institute of Physics. [S0021 - 9606(00)30739-5].