A mechanistic study concerning the carbon-silicon bond cleavage in acylsilane bioreductions

Authors
Patrocinio, AF Moran, PJS
Citation
Af. Patrocinio et Pjs. Moran, A mechanistic study concerning the carbon-silicon bond cleavage in acylsilane bioreductions, J CHEM R-S, (8), 2000, pp. 404-405
Citations number
28
Categorie Soggetti
Chemistry
Journal title
JOURNAL OF CHEMICAL RESEARCH-S
ISSN journal
03082342 → ACNP
Issue
8
Year of publication
2000
Pages
404 - 405
Database
ISI
SICI code
0308-2342(200008):8<404:AMSCTC>2.0.ZU;2-L
Abstract
Some mechanistic proposals are made for the competitive desilylation reacti ons affording the corresponding primary alcohol and carboxylic acid that fr equently occur in the bioreduction of acylsilanes.