It has been shown that in semi-insulating films, the characterization of ch
arge transport phenomena, such as dielectric relaxation, by resistance and
capacitance only is insufficient. The independent roles played by additiona
l transport parameters, including charge injection, trapping and field depe
ndent mobility, are elucidated by a first principle treatment of charge tra
nsports in both the closed circuit and open circuit modes. Experimental res
ults from typical electrophotographic paper and charging roll samples are c
ompared with the results of mathematical simulations. The advantage of open
circuit measurements, such as Electrostatic Charge Decay (ECD), is noted.