Spherical particles of alpha-Fe2O3 80 to 100 nm in size were prepared with
the polyol method. Scanning electron microscopy, x-ray powder diffraction,
and measurements of the diffuse reflection were used to characterize the po
wder material. The characteristic red color of hematite was adjusted after
brief heating (250 degrees C, 15 min) which did not lead to further particl
e growth. The polyol method turned out to be suited for the preparation of
quite concentrated (up to 20 wt%) and very stable suspensions of submicron
Fe2O3 particles. Based on such suspensions, the red emitting phosphor Y2O2S
:Eu was coated as a model substrate. As a result, very homogeneous coatings
of alpha-Fe2O3 on the phosphor material were realized. Individual iron oxi
de particles on the phosphor surface confirm the presence of nonagglomerate
d Fe2O3 particles in the polyol medium.