St. Lee et al., PRESSURE EFFECT ON DIAMOND NUCLEATION IN A HOT-FILAMENT CVD SYSTEM, Physical review. B, Condensed matter, 55(23), 1997, pp. 15937-15941
Using extraordinarily low pressure (0.1-1 Torr) we obtained high-densi
ty nucleation of diamond on mirror-polished silicon in a hot-filament
chemical vapor deposition (HF-CVD) system. A diamond nuclei density as
high as 10(10)-10(11) cm(-2) was achieved, which was comparable to th
e largest nuclei density obtained in a microwave-plasma chemical vapor
deposition system. The low-pressure nucleation technique and the pres
sure effect on diamond nucleation were discussed in detail based on mo
lecular dynamics. The enhanced nucleation at low pressure was attribut
ed to an increased mean free path, which gave rise to an increased con
centration of nucleating species at the substrate and other beneficial
nucleating factors. The present work suggests that very low pressure
may be an effective approach to nucleate and grow diamond films on unt
reated substrates via HF-CVD.