Photochemistry of the 8-quinolinol adduct of methyltrioxorhenium(VII)

Authors
Kunkely, H Vogler, A
Citation
H. Kunkely et A. Vogler, Photochemistry of the 8-quinolinol adduct of methyltrioxorhenium(VII), J PHOTOCH A, 136(3), 2000, pp. 175-177
Citations number
37
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
ISSN journal
10106030 → ACNP
Volume
136
Issue
3
Year of publication
2000
Pages
175 - 177
Database
ISI
SICI code
1010-6030(20000929)136:3<175:POT8AO>2.0.ZU;2-3
Abstract
MeReO3 forms a violet adduct with oxine (8-quinolinol or 8-hydroxyquinoline ). MeReO3(oxine) shows a long-wavelength absorption at lambda(max) = 540 nm which is assigned to a. CH3- --> oxine (ligand-ligand charge transfer) tra nsition. LLCT excitation leads to the formation of methane and ReO3(oxinate ) as stable photoproducts with phi = 0.0015 at lambda(irr) = 546 nm in CH3C N. (C) 2000 Elsevier Science S.A. All rights reserved.