Photodissociation dynamics of hydrated Ni2+ clusters: Ni2+(H2O)(n) (n=4-7)

Hydrated divalent nickel clusters, Ni2+(H2O)(n) (n = 4-7), have been genera ted through electrospray ionization and studied with laser photofragment sp ectroscopy. Clusters containing six and seven water molecules dissociate by loss of either one or two water molecules. in contrast, Ni2+(H2O)(4) disso ciates via charge reduction, producing H3O+ + NiOH+(H2O)(2). The modest kin etic energy release in the H3O+ product is in agreement with a salt-bridge dissociation mechanism. Observed dissociation cross-sections indicate that the hexahydrated species is the probable carrier for nickel's aqueous absor ption spectrum.