Jm. Borrego et al., Devitrification process of FeSiBCuBbX nanocrystalline alloys: Mossbauer study of the intergranular phase, J PHYS-COND, 12(37), 2000, pp. 8089-8100
Mossbauer experiments were performed at room temperature using different ex
perimental configurations on several series of nanocrystalline FeSiBCuNbX a
lloys (X = Zr, Nb, Mo and V) obtained after annealing treatments of melt-sp
un ribbons. The refinement of Mossbauer spectra allows the kinetics and the
local structural rearrangement mechanisms associated with the nanocrystall
ization process to be compared. The hyperfine field distributions of the in
tergranular phase show the emergence of a bimodal behaviour that becomes si
gnificantly more pronounced from volumetric crystalline fractions estimated
at similar to 20-25%, regardless of the nature of the substituting element
. The hyperfine field distribution can be described by means of two Gaussia
n components, consistent with of a two-cluster-like model. Such a behaviour
can be attributed to the presence of iron-rich and iron-poor zones within
the intergranular phase, resulting from the diffusion process. These mechan
isms are found to be independent of the nature of X. In addition, strong in
-plane magnetic structures are evidenced for Nb-, Mo-, and V-based systems
while the magnetic domains tend to be randomly distributed in Zr-based nano
crystalline alloys.